Full Download The Privileged Pincer-Metal Platform: Coordination Chemistry & Applications - Gerard Van Koten | ePub
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Gerard van koten: the mono-anionic ece-pincer ligand - a versatile privileged ligand platform: general considerations. - elena poverenov, david milstein: non-innocent behavior of pcp and pcn pincer ligands of late metal complexes. Roddick: tuning of pcp pincer ligand electronic and steric properties.
The privileged pincer-metal platform coordination ~ (2016) 순서 [원서] (topics in organometallic chemistry 54) gerard van koten, robert a gossage (eds.
Ligand development plays an essential role in the advance of homogeneous catalysis. Tridentate, meridionally coordinating ligands, commonly termed pincer ligands, have been established as a privileged class of ligands in catalysis because they confer high stability while maintaining electronic tenab.
During the past 40 years, the monoanionic, tridentate ligand platform that has been named “pincer” has established itself as a privileged ligand in a variety of research and application areas.
Since the first pincer complexes were reported in the 1970s, this class of materials has greatly expanded and now the ligand framework is often referred to as one of the “privileged” classes of metal binding agents.
Bi- and trinuclear copper(i) complexes of 1,2,3-triazole-tethered nhc ligands: synthesis, structure, and catalytic properties.
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Recent advances in alkane dehydrogenation catalyzed by pincer complexes.
The monoanionic pincer–metal platform: which is a well-established privileged ligand with a proven potential in a wide range of applications.
The privileged pincer metal platform coordination chemistry applications. Author: gerard van koten,robert a gossage: publsiher: springer: total pages: 374: release.
The privileged pincer metal platform coordination chemistry applications book description the series topics in organometallic chemistry presents critical overviews of research results in organometallic chemistry.
Pincer complexes are formed by the binding of a chemical structure to a metal atom with at least one carbon-metal bond. Usually the metal atom has three bonds to a chemical backbone, enclosing the atom like a pincer.
We report here the synthesis, single-crystal structure, electrospray mass spectrum and nmr spectroscopy of a new six-coordinate cobalt(ii) pincer complex. The pincer ligand, in this complex, which is novel, coordinates via three nitrogen atoms (two triazole and one pyridine). The ligand is ambidentate and can coordinate via three nitrogen atoms or two sulfur and one nitrogen atoms.
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Topics in organometallic chemistry current research reports and chronological list of recent articles.
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Since the first pincer complexes were reported in the 1970s, this class of materials has greatly expanded and now the ligand framework is often referred to as one of the “privileged” classes of metal binding agents.
The pincer platform provides increased stability and often a rigid coordination mode in transition metal complexes that allows for the incorporation of reactive.
The synthesis, structural characterization, and reactivity of the first example of a scandium -substituted nitrilimine are presented. This unique complex exhibits high thermal stability but shows a rich reactivity toward a variety of unsaturated substrates, including aldehyde, ketone, nitrile, and allene derivatives. The versatility of the complex was further highlighted by density functional.
Pincer complexes are formed by the binding of a chemical structure to a metal a donor atom in the side arms have been known as a privileged pincer platform.
Particular interest has been directed to study (reversible) c-c bond formation and bond cleavage (1978) processes on the pincer-metal platform. Karl kirchner is presently professor of organometallic chemistry at the technical university of vienna (tu wien).
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